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In a free-standing membrane, atoms can ripple out of the plane (z-direction) with ease. These low-energy dominate the thermal and electronic behavior. Unlike in bulk, these modes have a quadratic (rather than linear) dispersion. They cause a strange effect: thermal conductivity decreases as temperature increases —opposite to most solids—and they can lead to a giant, tunable negative thermal expansion coefficient. In a free-standing membrane, atoms can ripple out